preparation of high surface area zro2 nanoparticles
Authors
abstract
in comparison to the previous researches, zro2 nanoparticles with higher surface area (85 m2/g) have been synthesized in this research. the as-prepared zro2 nanoparticles by co-precipitation method were characterized with x-ray diffraction (xrd), scanning electron microscopy (sem) and transmission electron microscopy (tem). the surface area of the sample was characterized by bet method. the effect of the growth parameters such as temperature, ph, zr4+/template ratio and kind of template on the growth and morphology of zro2 nanoparticles have been investigated in detail. the results revealed that ph, temperature, zr4+/template and kind of template have an important effect on the morphology and size of the zro2 nanoparticles. x ray diffraction (xrd) analysis of the superior nanoparticles that was prepared at ph=4, temperature=70 oc, zr4+/template ratio=2 and by sorbitol as template indicates the formation of nanocrystalline zro2tetragonal phase structure. the average particle size of the product is about 4.45 nm that was calculated from xrd pattern by the debye-scherrer formula.
similar resources
Preparation of High Surface Area ZrO2 Nanoparticles
In comparison to the previous researches, ZrO2 nanoparticles with higher surface area (85 m2/g) have been synthesized in this research. The as-prepared ZrO2 nanoparticles by co-precipitation method were characterized with X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM). The surface area of the s...
full textPreparation and Characterization of High Specific Surface Area γ-Alumina Nanoparticles Via Sol-Gel Method
In the present investigation, γ-alumina nanoparticles with particle sizes less than 10 nm, high specific surface area (351 m2/g), high pore volumes and relatively narrow pore sizes distribution was prepared via sol-gel method in presence of aluminum isopropoxide as an aluminum precursor, distilled water, acetic acid as hydrolysis rate controller and tert-butanol as solvent. They had meso ...
full textZrO2 bubbles from core–shell nanoparticles{
Selective removal of metal cores from core–shell Ag@ZrO2 (ZrO2 coated Ag) and Au@ZrO2 (ZrO2 coated Au) nanoparticles result in stable and freely suspendable oxide nanobubbles of varying dimensions, both in thickness and in diameter. The metal core is removed by a newly found reaction in which halocarbons, generally chlorides, oxidise the metal core and leach out the metal ions. Reduction in the...
full textLight-Controlled ZrO2 Surface Hydrophilicity
In recent years many works are aimed at finding a method of controllable switching between hydrophilicity and hydrophobicity of a surface. The hydrophilic surface state is generally determined by its energy. Change in the surface energy can be realized in several different ways. Here we report the ability to control the surface wettability of zirconium dioxide nano-coatings by changing the comp...
full textSol-gel preparation of low oxygen content, high surface area silicon nitride and imidonitride materials.
Reactions of Si(NHMe)4 with ammonia are effectively catalysed by small ammonium triflate concentrations, and can be used to produce free-standing silicon imide gels. Firing at various temperatures produces amorphous or partially crystallised silicon imidonitride/nitride samples with high surface areas and low oxygen contents. The crystalline phase is entirely α-Si3N4 and structural similarities...
full textPreparation of high-surface-area zinc oxide with ordered porosity, different pore sizes, and nanocrystalline walls.
Transition-metal-oxide materials possessing ordered mesoporosity have recently attracted significant research interest due to their numerous potential applications. Among them, ordered mesoporous zinc oxide (ZnO) is a very tempting material because of the importance of ZnO in heterogeneous catalysis. Here, first results of the preparation of ordered mesoporous ZnO materials by using different t...
full textMy Resources
Save resource for easier access later
Journal title:
iranian journal of chemistry and chemical engineering (ijcce)Publisher: iranian institute of research and development in chemical industries (irdci)-acecr
ISSN 1021-9986
volume 33
issue 2 2014
Hosted on Doprax cloud platform doprax.com
copyright © 2015-2023